![]() Explosive composition
专利摘要:
1510216 Explosive compositions CANADIAN INDUSTRIES Ltd 6 April 1976 [8 May 1975] 19381/75 Addition to 1456814 Heading CID A thickened aqueous explosive composition as claimed in the parent Specification is modified by the omission of the self-explosive sensitizer. The foaming and stabilizing surfactants are in general the same as those referred to in the parent Specification, but an additional foaming surfactant is lauryl ammonium sulphonic acid betaine. Inorganic oxygen-supplying salts, thickeners, thickener cross-linkers, fuels, and other ingredients are as specified in the Present Specification, with the addition of sulphur in one example. The composition is detonable in diameters greater than 5À1 cm. and may be packed into cartridges or pumped into boreholes. 公开号:SU932981A3 申请号:SU762353718 申请日:1976-05-07 公开日:1982-05-30 发明作者:Пол Ричард Джин 申请人:Канейдиан Индастриз Лимитед (Фирма); IPC主号:
专利说明:
The invention relates to industrial water-filled explosive compositions intended for blasting operations in mining enterprises, g Known water-filled explosive composition based on nitrates of ammonium, sodium, potassium, magnesium or calcium salts, water soluble mononitrag glycerol mononitrate ethylene or JQ metilaminonitrata et al., Water, ethylene glycol or glycerine, powdered aluminum or silicon, carbon, gelling agent, e.g., hydroxide ethyl cellulose or guar jj resin, a chromium acetate crosslinking agent or a potassium salt of pyrosurmic acid and glass microspheres Ll The disadvantage of this water-filled explosive composition is the inadequate susceptibility to detonation from the initiating impulse vi, difficulty in manufacturing due to ol. Number of used components .25 Closest to the invention is an explosive composition containing by weight 10-30 sodium nitrate, 3-20 water, 5-251 oxyalk nitrate or alkylaminonitrate, powdered aluminum or silicon, 0.110 mixtures of stabilizing and hardening surfactants from aliphatic alcohols or amines with the number of carbon atoms Cj 2 and metal alkyl sulphates or salts of cyntransformed alcohols, 0,, 0% modified; cedarized guar gum, 0.022, 09th zinc chromate or potassium salt of pyrosurmic acid, and the rest to (0% ammonium nitrate 2. The presence in the specified explosive composition of scarce and rare oxyalkyl nitrates or alkylaminonitrates considerably increases the cost of manufacture of explosives. The purpose of the invention is to develop a cheaper explosive composition without sensitizers sensitive to detonation from a detonator cap, ensuring the completeness of an explosion in charges with a diameter of 51 mm or less. This goal is achieved by the fact that in the explosive composition the components are taken in the following ratio, weight .; Sodium nitrate or calcium 8-15. Ethylene glycol 5 Guar resin O, A - 2.0 Water 10-20 Zinc chromate. 0.02-2.0 9329 S 10 4 A mixture of stabilizing and foaming surfactants, predominantly ethoxylated ammonium, lauryl sulfate and stearyl amine or bechininyl amine, with the number of carbon atoms in the ratio 1: 0,, 5 0.1 - 10 Ammonium nitrate Else. Table 1 71.72 86.92 15.0 About, About About, About 0.5 0.5 . 12.0 12.0 0.72 0.52 Density - after cooking - after storage 7.2i 10 5 0.06 .10.00, 7 1.0 1.06 1.12 1.20 "The diameter of the cartridges, mm paper shell) Sensitivity to detonation at temperature, -2, from the initiating impulse of pentolite (50/50), g Under the same conditions, samples without stabilizing surfactants are not detonated from pentolite (50/50) with a weight of IO-1 gOg at + 15.5 ° e. Note: optional components zinc nitrate aluminum, sulfur, diatomaceous earth and gilsonite composition of samples 1- are not included.
权利要求:
Claims (2) [1] Invention Formula An explosive composition based on ammonium nitrate, sodium or calcium nitrate, ethylene glycol, guar gum, zinc chromate and a mixture of stabilizing and foaming surfactants taken in the ratio of 1: 0,: 6.5, from aliphatic alcohols or amines with carbon numbers Ci 22 atoms characterized in that, in order to provide increased susceptibility to detonation without sensitization 51 76.2 127 101.6 20 160 20 0 Detonation is full ditch, it contains components in a ratio, wt.%: Sodium or calcium nitrate 8 Ethylene glycol Water 10 Guar gum O, Zinc chromate 0.02 A mixture of stabilizing and foaming surfactants, mainly ethoxylated ammonium, lauryl sulfate and stearyl amine or bechinyl amine with the number of carbon atoms Cj2-C22 in relation to ItO, - 1: 6.5 0.1 Ammonium nitrate Osta Sources of information taken into account by experts, 1. US Patent ff 365.3992, cl. publish t.OA.72. [2] 2. Patent of the USSR No. 53762, cl. C About B 31/28, C 06 B 31/02, 21.02.7 (prototype).
类似技术:
公开号 | 公开日 | 专利标题 US4310364A|1982-01-12|Emulsion explosive sensitive to a detonator US2463709A|1949-03-08|Ammonium nitrate explosive SU932981A3|1982-05-30|Explosive composition SU537624A3|1976-11-30|Explosive composition GB979729A|1965-01-06|Explosive gel composition US3431155A|1969-03-04|Water-bearing explosive containing nitrogen-base salt and method of preparing same US3356544A|1967-12-05|Inorganic oxidizer salt aqueous blasting compositions containing a nitroparaffin US3653992A|1972-04-04|Aqueous slurry salt type explosives containing nitrato-alkanol as sensitizer component and manufacture thereof US3390032A|1968-06-25|Gelled aqueous slurry explosive composition containing as a gas generating agent a carbonate or bicarbonate with a nitrite US3617404A|1971-11-02|Slurryxplosives containing the combination of nitrogen-base salt and hard solid particles as sensitizer GB1384859A|1975-02-26|Process for the production of crosslinked gums US3966516A|1976-06-29|Slurry explosive composition containing a nitroparaffin and an amide SU698527A3|1979-11-15|Water-filled explosive composition US3401067A|1968-09-10|Aqueous slurry type explosive compositions sensitized with at least one alkanolamine nitrate EP0011383B1|1982-03-31|Gelled aqueous slurry explosives containing gas bubbles GB1396458A|1975-06-04|Explosive compositions GB989295A|1965-04-14|Boron compound US3318740A|1967-05-09|Aqueous slurry-type blasting compositions containing a hexamethylene-tetramine nitrate sensitizer GB1317328A|1973-05-16|Slurry explosives US3546034A|1970-12-08|Ammonium nitrate-nitromethane type blasting agent containing urea as a crystallization inhibitor US3000955A|1961-09-19|Dinitramines GB1002671A|1965-08-25|Slurried blasting explosives US3390031A|1968-06-25|Gelled aqueous slurry explosive composition containing an inorganic nitrite US3159678A|1964-12-01|Nitramines US3681156A|1972-08-01|Slurried blasting explosive containing as sensitizing ingredient liquid non-explosive alkyl nitrate
同族专利:
公开号 | 公开日 FI61470C|1982-08-10| NO141011B|1979-09-17| GB1510216A|1978-05-10| IT1061238B|1983-02-28| ZM5476A1|1978-02-21| RO72151A|1982-05-10| ZA762356B|1977-12-28| JPS5231814A|1977-03-10| BR7602728A|1976-11-16| CA1075008A|1980-04-08| AU1287176A|1977-10-13| IL49364A|1979-07-25| FR2310325B2|1980-05-09| ES447678A2|1977-07-01| FI761296A|1976-11-09| IE44148B1|1981-08-26| DD126045A5|1977-06-15| NO141011C|1979-12-27| BR7602851A|1976-11-16| FR2310325A2|1976-12-03| SE7605197L|1976-11-09| IN142336B|1977-06-25| DE2620097A1|1976-11-18| BE841310R|1976-10-29| SE426166B|1982-12-13| HK66478A|1978-11-24| IL49364D0|1976-09-30| IE44148L|1976-11-08| PH13658A|1980-08-21| DE2620097C3|1978-10-05| PL101868B1|1979-02-28| NO761453L|1976-11-09| FI61470B|1982-04-30| US4026738A|1977-05-31| AR214503A1|1979-06-29| DE2620097B2|1978-01-05| CS194760B2|1979-12-31|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 US3447978A|1967-08-03|1969-06-03|Atlas Chem Ind|Ammonium nitrate emulsion blasting agent and method of preparing same| US3471346A|1968-01-25|1969-10-07|Du Pont|Fatty alcohol sulfate modified water-bearing explosives containing nitrogen-base salt| GB1214245A|1968-04-24|1970-12-02|Sumitomo Chemical Co|Explosive compositions| GB1270319A|1969-09-05|1972-04-12|Ireco Chemicals|Method for preparing slurry explosive compositions of variable and controlled density| GB1306546A|1970-06-09|1973-02-14|Explosives & Chem Prod|Blasting explosive composition|NZ185663A|1976-11-29|1980-05-08|Ici Australia Ltd|Explosive compositions-explosive componentlocated in and immobilised by a rigid foamednon-explosive matrix| JPS5742596B2|1978-11-30|1982-09-09| US4453989A|1982-04-05|1984-06-12|Atlas Powder Company|Solid sensitizers for water-in-oil emulsion explosives| JPS6152963A|1984-08-22|1986-03-15|Sukai Alum Kk|Production of composite metallic material| NO160770C|1986-10-03|1989-05-31|Dyno Industrier As|PROCEDURE AND DEVICE FOR PATTERNING OF ADHESIVE EXPLOSIVES.| IL144961D0|1999-02-19|2002-06-30|Foam formulations| US6539870B1|2000-11-22|2003-04-01|Dyno Nobel Inc.|Blasting method for reducing nitrogen oxide fumes| EP2784052A1|2013-03-27|2014-10-01|Maxamcorp Holding, S.L.|Method for the "on-site" manufacture of water-resistantlow-density water-gel explosives|
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申请号 | 申请日 | 专利标题 GB19381/75A|GB1510216A|1975-05-08|1975-05-08|Stabilized foamed water gel explosives| 相关专利
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